ROTATIONAL DEPENDENCE OF CORIOLIS AND FERMI TYPE RESONANCES IN SMALL LINEAR MOLECULES

M. . Smirnov


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Abstract

The dependence of effective parameters in model Hamiltonian is investigated from the point of view of applied ordering scheme of oscillatory rotational interactions. Relations for transformation generators in different ordering schemes of oscillatory rotational interactions are formulated by “disentanglement” technique. The operator of resonance interaction is selected from general operator in effective rotational Hamiltonian on the
base of projection operator technique. At strong resonance interaction the dependence from ordering of oscillatory rotational interactions is shown to be weaker than for the cases of middle and weak resonances.


Keywords: oscillatory rotational interactions, Fermi and Coriolis type resonances, ordering schemes of oscillatory rotational interactions
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