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	A study of a silicone film deposited on quartz glass under laser radiation </div>

Belikov Andrey V., Klochkov Ivan S. , Alekseev Ivan V. , Kapralov Sergey A.

2022 , VOLUME 22, NUMBER 1 ( january-february )

ISSN 2226-1494 (print), ISSN 2500-0373 (online)

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Nikiforov
Vladimir O.
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doi: 10.17586/2226-1494-2022-22-1-1-9

A study of a silicone film deposited on quartz glass under laser radiation

A. V. Belikov, I. S. Klochkov, I. V. Alekseev, S. A. Kapralov

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Article in Russian

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Belikov A.V., Klochkov I.S., Alekseev I.V., Kapralov S.A. A study of a silicone film deposited on quartz glass under laser radiation. Scientific and Technical Journal of Information Technologies, Mechanics and Optics, 2022, vol. 22, no. 1, pp. 1–9 (in Russian). doi: 10.17586/2226-1494-2022-22-1-1-9

Abstract

The paper studies the structure, optical and operational properties of a silicone film deposited on the surface of quartz glass as a result of the action of laser radiation on volatile substances released from a silicone rubber sample in a closed volume. The research was carried out within the framework of the laser multiparameter method and using an original setup, which includes a solid-state neodymium laser with a wavelength of 1064 nm, and laser pulse parameters: energy of 105 mJ, a duration of 11–14 ns, a repetition rate of 10 Hz. A sealed test-cuvette is placed at the output of the laser. A silicone rubber sample is placed inside the test-cuvette. When laser radiation passes through the test-cuvette, volatile substances that are released from the sample over time interact with the laser radiation and create deposition zones on the optical elements of the test-cuvette, which affect the optical characteristics of these optical elements. The topology of the deposition zones was studied using a profilometer. The structural composition of the original silicone rubber and the deposition zone was determined using a scanning electron microscope. The main results show the dependences of the coefficients of the area and attenuation of the deposition zone on the temperature and the number of laser pulses. The elemental composition, color, resistance to the action of the solvent, and the thickness of the deposition zones have been investigated. It was found that with an increase in the temperature and the number of laser pulses, the area and attenuation coefficients of the deposition zones increase, the color does not change, and the resistance to the action of the solvent increases. With an increase in temperature, the deposition zone, initially consisting of micro-fragments, becomes continuous, and with an increase in the number of laser pulses, its thickness increases. The thickness of the deposition zone is unevenly distributed along its diameter. The results obtained can be applied in the development of silicone-containing biochips for health diagnostics and therapy.

Keywords: laser multiparameter method, sealed volume, test-cuvette, attenuation, deposition zone, silicone rubber

References

Kamaly N., Yameen B., Wu J., Farokhzad O.C. Degradable controlled-release polymers and polymeric nanoparticles: mechanisms of controlling drug release. Chemical Reviews, 2016, vol. 116, no. 4, pp. 2602–2663. https://doi.org/10.1021/acs.chemrev.5b00346
Barkalina N., Charalambous C., Jones C., Coward K. Nanotechnology in reproductive medicine: emerging applications of nanomaterials. Nanomedicine: Nanotechnology, Biology and Medicine, 2014, vol. 10, no. 5, pp. e921–e938. https://doi.org/10.1016/j.nano.2014.01.001
Furth M.E., Atala A., Van Dyke M.E. Smart biomaterials design for tissue engineering and regenerative medicine. Biomaterials, 2007, vol. 28, no. 34, pp. 5068–5073. https://doi.org/10.1016/j.biomaterials.2007.07.042
Gandhi A., Paul A., Sen S.O., Kumar K.S. Studies on thermoresponsive polymers: Phase behaviour, drug delivery and biomedical applications. Asian Journal of Pharmaceutical Sciences, 2015, vol. 10, no. 2, pp. 99–107. https://doi.org/10.1016/j.ajps.2014.08.010
Suhardi V.J., Bichara D.A., Kwok S.J.J., Freiberg A.A., Rubash H., Malchau H., Yun S.H., Muratoglu O.K., Oral E. A fully functional drug-eluting joint implant. Nature Biomedical Engineering, 2017, vol. 1, no. 6, pp. 0080. https://doi.org/10.1038/s41551-017-0080
Masood F. Polymeric nanoparticles for targeted drug delivery system for cancer therapy. Materials Science and Engineering: C, 2016, vol. 60, pp. 569–578. https://doi.org/10.1016/j.msec.2015.11.067
Ulbrich K., Holá K., Šubr V., Bakandritsos A., Tuček J., Zbořil R. Targeted drug delivery with polymers and magnetic nanoparticles: covalent and noncovalent approaches, release control, and clinical studies. Chemical Reviews, 2016, vol. 116, no. 9, pp. 5338–5431. https://doi.org/10.1021/acs.chemrev.5b00589
Soppimath K.S., Aminabhavi T.M., Kulkarni A.R., Rudzinski W.E. Biodegradable polymeric nanoparticles as drug delivery devices. Journal of Controlled Release, 2001, vol. 70, no. 1-2, pp. 1–20. https://doi.org/10.1016/S0168-3659(00)00339-4
Mokhtarzadeh A., Alibakhshi A., Hejazi M., Omidi Y., Ezzati Nazhad Dolatabadi J. Bacterial-derived biopolymers: Advanced natural nanomaterials for drug delivery and tissue engineering. TrAC Trends in Analytical Chemistry, 2016, vol. 82, pp. 367–384. https://doi.org/10.1016/j.trac.2016.06.013
Luo D., Gould D.J., Sukhorukov G.B. Local and sustained activity of doxycycline delivered with layer-by-layer microcapsules. Biomacromolecules, 2016, vol. 17, no. 4, pp. 1466–1476. https://doi.org/10.1021/acs.biomac.6b00070
Wang C., Zhang G., Liu G., Hu J., Liu S. Photo-and thermo-responsive multicompartment hydrogels for synergistic delivery of gemcitabine and doxorubicin. Journal of Controlled Release, 2017, vol. 259, pp. 149–159. https://doi.org/10.1016/j.jconrel.2016.11.007
Sukhorukov G.B., Donath E., Lichtenfeld H., Knippel E., Knippel M., Budde A., Möhwald H. Layer-by-layer self assembly of polyelectrolytes on colloidal particles. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 1998, vol. 137, no. 1-3, pp. 253–266. https://doi.org/10.1016/S0927-7757(98)00213-1
Dhoot N.O., Wheatley M.A. Microencapsulated liposomes in controlled drug delivery: strategies to modulate drug release and eliminate the burst effect. Journal of Pharmaceutical Sciences, 2003, vol. 92, no. 3, pp. 679–689. https://doi.org/10.1002/jps.19104
Gai M., Frueh J., Kudryavtseva V.L., Mao R., Kiryukhin M.V., Sukhorukov G.B. Patterned microstructure fabrication: polyelectrolyte complexes vs polyelectrolyte multilayers. Scientific Reports, 2016, vol. 6, pp. 37000. https://doi.org/10.1038/srep37000
Gai M., Frueh J., Tao T., Petrov A.V., Shesterikov E.V., Tverdokhlebov S.I., Sukhorukov G.B. Polylactic acid nano- and microchamber arrays for encapsulation of small hydrophilic molecules featuring drug release via high intensity focused ultrasound. Nanoscale, 2017, vol. 9, no. 21, pp. 7063–7070. https://doi.org/10.1039/C7NR01841J
Belikov A.V., Klochkov I.S., Alekseev I.V., Kapralov S.A. Laser multiparameter method for incoming inspection of the mounting elements used in the volume of sealed neodymium laser emitters. Scientific and Technical Journal of Information Technologies, Mechanics and Optics, 2021, vol. 21, no. 2, pp. 154–162. (in Russian). https://doi.org/10.17586/2226-1494-2021-21-2-154-162
Schneider C.W., Lippert T. Laser ablation and thin film deposition. Springer Series in Materials Science, 2010, vol. 139, pp. 89–112. https://doi.org/10.1007/978-3-642-13281-0_5
Krebs H.-U., Weisheit M., Faupel J., Süske E., Scharf T., Fuhse C., Störmer M., Sturm K., Seibt M., Kijewski H., Nelke D., Panchenko E., Buback M. Pulsed laser deposition (PLD) - a versatile thin film technique. Advances in Solid State Physics, 2003, vol. 43, pp. 505–518. https://doi.org/10.1007/978-3-540-44838-9_36
Dler A. Thin film deposition processes. International Journal of Modern Physics and Applications, 2015, vol. 1, no. 4, pp. 193–199.
Wasa K., Kitabatake M., Adechi H. Thin Film Materials Technology: Sputtering of Compound Materials. Walliam Andrew Inc, 2004, pp. 1.
Fominski V.Yu., Romanov R.I., Nevolin V.N., Gnedovets A.G. Features of metal oxide thin film formation in Pt/WOx/SiC gas sensor device by pulsed laser deposition. Perspektivnye materialy, 2011, no. 2, pp. 5–16. (in Russian)
Kulinich S.A., Yamaki T., Miyazoe H., Yamamoto H., Terashima K. Effect of the substrate temperature and deposition rate on the initial growth of thin lithium niobate-tantalate films deposited from a thermal plasma. Physics of the Solid State, 2006, vol. 48, no. 5, pp. 904–911. https://doi.org/10.1134/S1063783406050155
Tsaplin S.V., Bolychev S.A. Research of the dynamics of condensed product deposition. Vestnik of Samara University Aerospace and Mechanical Engineering, 2014, vol. 14, no. 3, pp. 109–121. (in Russian). https://doi.org/10.18287/1998-6629-2014-0-3(45)-109-121
Pupan L.I. The study of material structure by electron microscopy: guidelines for laboratory research on the course "Introduction to nanotechnologies". Kharkiv, Kharkiv Polytechnic Institute, 2011, 35 p. (in Russian)

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