SPECTRAL AND LUMINESCENT PROPERTIES OF CHROMIUM IONS IN FORSTERITE-LIKE NANO-GLASS CERAMICS

V. A. Aseev, S. N. Zhukov, N. V. Kuleshov, S. V. Kurilchik, A. V. Mudryi, N. V. Nikonorov, A. S. Rokhmin, A. S. Yasyukevich


Read the full article  ';
Article in Russian


Abstract

Comparative analysis of spectral and luminescent properties for glasses SiO2-Al2O3-MgO-K2O-TiO2 doped with chromium ions and forsterite nano-glass ceramic have been done. Initial glasses were obtained by using a conventional melt quenching method. Glass ceramics were produced by the two-stage secondary heat treatment of initial glasses. At the first step of the heat treatment nucleation centers were formed at 700º C. At the second step there was an increase of Mg2SiO4: Cr crystalline phase. Crystalline phase composition and the crystals size were determined by X-ray diffractometer. It is shown that the crystalline phase of Mg2SiO4 (forsterite) is precipitated during the heat treatment. Valency state and the chromium ion position in a forsterite or a glassy matrix are determined according to luminescence and absorption spectra. Identification of absorption and luminescence bands in initial and heat-treated samples is carried out. The dependence between spectral and luminescent properties of chromium and heat treatment modes is examined. The results demonstrate that ions of the trivalent and tetravalent chromium are transforming to the forsterite crystalline phase during the heat treatment, and a part of them remains in the glassy phase. Presented research results can be used for the development of glasses and nanoscale glassceramic for fiber tunable lasers and broadband optical amplifiers of a near infrared range which are used in information and telecommunication technologies.


Keywords: chromium ions spectral and luminescent properties, forsterite nano-glassceramic doped with chromium ions, alumino-silicate glasses

References
 1.     Aseev V.A., Nikonorov N.V., Ul'yashenko A.M., Przhevuskii A.K., Fedorov Yu.K. Spectroluminescence properties of highly concentrated ytterbium-erbium phosphate glasses for microlasers. Journal of Optical Technology, 2006, vol. 73, no. 3, pp. 164–169.
2.     Jaque D., Lagomacini J., Jacinto C., Catunda T. Continuous-wave diode-pumped Yb: glass laser with near 90% slope efficiency. Applied Physics Letters, 2006, vol. 89, no.12, art. no. 121101. doi: 10.1063/1.2345828
3.     Angert N.B., Borodin N.I., Garmash V.M., Zhitnyuk V.A., Okhrimchuk A.G., Siyuchenko O.G., Shestakov A.V. Lasing due to impurity color centers in yttrium aluminum garnet crystals at wavelengths in the range 1.35–1.45 μm. Sov. J. Quantum Electron, 1988, vol. 18, pp. 73–74.
4.     Petricevic V., Gayen S.K., Alfano R.R., Yamagishi K., Anzai H., Yamaguchi Y. Laser action in chromium-doped forsterite. Applied Physics Letters, 1988, vol. 52, no.13, pp. 1040–1042. doi: 10.1063/1.99203
5.     Verdun H.R., Thomas L.M., Andrauskas D.M., McCollum T., Pinto A. Chromium-doped forsterite laser pumped with 1.06 mm radiation. Applied Physics Letters, 1988, vol. 53, no. 26, pp. 2593–2595. doi: 10.1063/1.100537
6.     Carrig T.J., Pollock C.R. Performance of a continuous-wave forsterite laser with krypton ion, Ti: sapphire, and Nd: YAF pump lasers. IEEE Journal of Quantum Electron, 1993, vol. 29, no. 11, pp. 2835–2844. doi: 10.1109/3.248943
7.     Beall G.N. Glass-ceramics for photonic applications. Glass Science and Technology: Glastechnische Berichte, 2000, vol. 73, no. 1 suppl. C, pp. 3–11.
8.     Ulyashenko A.M., Nikonorov N.V., Przhevuskii A.K. Forsterite nano glass-ceramics doped with CR4+ ions for fiber lasers and amplifiers. Bulletin of the Russian Academy of Sciences: Physics, 2007, vol. 71, no. 2, pp. 159–163. doi: 10.3103/S1062873807020049
9.     Subbotin K.A., Smirnov V.A., Zharikov E.V., Iskhakova L.D., Senin V.G., Voronov V.V., Shcherbakov I.A. Nano-glass-ceramics containing chromium-doped LiGaSiO4 crystalline phases. Optical Materials, 2010, vol. 32, no. 9, pp. 896–902. doi: 10.1016/j.optmat.2010.01.016
10.  Sharonov M.Yu., Bykov A.B., Owen S., Petricevic V., Alfano R.R., Beall G.H., Borelli N. Spectroscopic study of transparent forsterite nanocrystalline glass–ceramics doped with chromium. Journal of the Optical Society of America B: Optical Physics, 2004, vol. 21, no. 11, pp. 2046–2052.
11.  Stookey S.D. Ceramic body and method of making it. Patent US, no. 2971853, 1961.
12.  Jia W., Liu H., Jaffe S., Yen W.M., Denker B. Spectroscopy of Cr3+ and Cr4+ ions in forsterite. Physical Review B, 1991, vol. 43, no. 7, pp. 5234–5242. doi: 10.1103/PhysRevB.43.5234
13.  Petricevic V. Laser and Spectroscopic Properties of Chromium-Doped Forsterite. PhD Dissertation. The City University of New-York, 1990, 137 p.
14.  Koepke C., Wishniewski K., Grinberg M., Russell D.L., Holliday K. Optical spectroscopy and excited state absorption of the ZAS (ZrO2-Al2O3-SiO2) glass doped with chromium. Journal of Luminescence, 1999, vol. 81, no. 4, pp. 301–312. doi: 10.1016/S0022-2313(99)00003-4
15.  Hommerich U., Eilers H., Yen W.M., Hayben J.S., Aston M.K. Near infrared emission at 1.35 μm in Cr doped glass. Journal of Luminescence, 1994, vol. 60-61, no. C, pp. 119–122.


Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License
Copyright 2001-2024 ©
Scientific and Technical Journal
of Information Technologies, Mechanics and Optics.
All rights reserved.

Яндекс.Метрика