Menu
Publications
2025
2024
2023
2022
2021
2020
2019
2018
2017
2016
2015
2014
2013
2012
2011
2010
2009
2008
2007
2006
2005
2004
2003
2002
2001
Editor-in-Chief
Nikiforov
Vladimir O.
D.Sc., Prof.
Partners
doi: 10.17586/2226-1494-2015-15-3-435-442
SYNTHESIS OF MULTI-LAYER SUBSTRATE FOR OBSERVING OF HYDROXYBENZOIC ACIDS MOLECULES BY SERS
Read the full article
';
Article in Russian
For citation: Yasenko E.A., Chelibanov V.P. Synthesis of multi-layer substrate for observing of hydroxybenzoic acids molecules by SERS. Scientific and Technical Journal of Information Technologies, Mechanics and Optics, 2015, vol.15, no. 3, pp. 435–442.
Abstract
For citation: Yasenko E.A., Chelibanov V.P. Synthesis of multi-layer substrate for observing of hydroxybenzoic acids molecules by SERS. Scientific and Technical Journal of Information Technologies, Mechanics and Optics, 2015, vol.15, no. 3, pp. 435–442.
Abstract
Subject of study. The paper deals with the results of the multilayer substrate synthesis having an effect of SERS from hydroxybenzoic acid molecules which are adsorbed on its surface. Methods. To produce SERS substrate we have applied colloid chemistry methods: washing of colloids using a laboratory centrifuge OPn-8, carrying out serial chemical reactions for modifying the surface of semiconductor particles of SiO2 in the solution, determining the maximum of the absorption spectrum of the substrate obtained (in the range from 400 to 1000 nm). To observe hydroxybenzoic acids molecules the method of Raman scattering on OPTEC-785 Video-M spectrometer has been used. Main results. A new method of the substrate chemical synthesis is proposed, which has the effect of SERS by radiationexcitation wavelength of 785 nm, based on micron silica particles with immobilized surface of gold and silver. Raman spectra of hydroxybenzoic acids (Gallic and p-hydroxybenzoic) in free and adsorbed state have been experimentally obtained and interpreted. It was shown that both acids in a crystalline state are in the form of dimers. Also, the presence of a certain group of characteristic bands indicates that the hydroxybenzoic acid is chemically bonded to the substrate surface through an oxygen bridge of deprotonated hydroxyl groups. However, unlike Gallic acid, p-hydroxybenzoic acid passes into the monomer form. Practical significance. This technique for enhancing substrate preparation is usable in the laboratory without sophisticated technical equipment. Experimental data on the method of securing the hydroxybenzoic acids and form of their existence on the surface of the substrate will be useful in the design of sensor systems based on them. Characteristic bands of undistorted aromatic ring of hydroxybenzoic acids may also be used in developing
Keywords: SERS, surface modification, Gallic acid, p-hydroxybenzoic acid, hydroxybenzoic acids.
References
References
1. Grasselli J.G. Chemical Applications of Raman Spectroscopy. Wiley, 1981, 208 p.
2. Emel'yanov V.I., Koroteev N.I. Giant Raman scattering of light by molecules adsorbed on the surface of a metal. Sov. Phys. Usp., 1981, vol. 24, pp. 864–873. doi: 10.1070/PU1981v024n10ABEH004812
3. Etchegoin P.G., Ru E.C.L. Basic electromagnetic theory of SERS. Surface Enhanced Raman Spectroscopy: Analytical, Biophysical and Life Science Applications. Ed. S. Schlucker. Wiley, 2010, pp. 1–37. doi: 10.1002/9783527632756.ch1
4. Zhang L.S., Fang Y., Zhang P. Laser-MBE of nickel nanowires using AAO template: a new active substrate of surface enhanced Raman scattering. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 2008, vol. 69, no. 1, pp. 91–95. doi: 10.1016/j.saa.2007.03.035
5. Schlegel V.L. Cotton T.M. Silver-island films as substrates for enhanced Raman scattering: effect of deposition rate on intensity. Analytical Chemistry, 1991, vol. 63, no. 3, pp. 241–247.
6. Zhang L., Zhang P., Fang Y. Magnetron sputtering of silver nanowires using anodic aluminum oxide template: a new active substrate of surface enhanced Raman scattering and an investigation of its enhanced mechanism. Analytica Chimica Acta, 2007, vol. 591, no. 2, pp. 214–218. doi: 10.1016/j.aca.2007.03.069
7. Zhang L.S., Fang Y., Zhang P.X. Experimental and DFT theoretical studies of SERS effect on gold nanowires array. Chemical Physics Letters, 2008, vol. 451, no. 1–3, pp. 102–105. doi: 10.1016/j.cplett.2007.11.077
8. Chattopadhyay S., Lo H.-C, Hsu C.-H., Chen L.-C., Chen K.-H. Surface enhanced Raman spectroscopy using self assembled silver nanoparticles on silicon nanotips. Chemistry of Materials, 2005, vol. 17, no. 3, pp. 553–559. doi: 10.1021/cm049269y
9. Ke W.H., Zhou D., Wu J., Ji K. Surface-enhanced Raman spectra of calf thymus DNA adsorbed on concentrated silver colloid. Applied Spectroscopy, 2005, vol. 59, no. 4, pp. 418–423.
10. Schmuck C., Wich P., Kustner B., Kiefer W., Schlucker S. Direct and label-free detection of solid-phasebound compounds by using surface-enhanced Raman scattering microspectroscopy. Angewandte Chemie - International Edition, 2007, vol. 46, no. 25, pp. 4786–4789. doi: 10.1002/anie.200605190
11. Leopold N., Lendl B. New method for fast preparation of highly surface-enhanced Raman scattering (SERS) active silver colloids at room temperature by reduction of silver nitrate with hydroxylamine hydrochloride.
Journal of Physical Chemistry B, 2003, vol. 107, no. 24, pp. 5723–5727.
12. Rivas L., Sanchez-Cortes S., Garcia-Ramos J.V., Morcillo G. Growth of silver colloidal particles obtained by citrate reduction to increase the Raman enhancement factor. Langmuir, 2001, vol. 17, no. 3, pp. 574–577. doi: 10.1021/la001038s
13. Pham T., Jackson J.B., Halas N.J., Lee T.R. Preparation and characterization of gold nanoshells coated with self-assembled monolayers. Langmuir, 2002, vol. 18, no. 12, pp. 4915–4920. doi: 10.1021/la015561y
14. Oldenburg S.J., Averitt R.D., Westcott S.L., Halas N.J. Nanoengineering of optical resonances. Chemical Physics Letters, 1998, vol. 288, no. 2–4, pp. 243–247.
15. Ferreira D.C., Rodrigues L.P., Madurro J.M., Madurro A.G.B., de Oliveira R.T.S. Jr., Abrahao O. Jr. Graphite electrodes modified with poly(3-hydroxybenzoic acid) for oligonucleotides sensors. Interanational Journal of Electrochemical Science, 2014, vol. 9, no. 11, pp. 6246–6257.
16. Deegan R.D, Bakajin O., Dupont T.F., Huber G., Nagel S.R., Witten T.A. Contact line deposits in an evaporating drop. Physical Review E – Statistical Physics, Plasmas, Fluids, and Related Interdisciplinary Topics, 2000, vol. 62, no. 1 B, pp. 756–765. doi: 10.1103/PhysRevE.62.756
17. Billes F., Mohammed-Ziegler I., Bombicz P. Vibrational spectroscopic study on the quantum chemical model and the X-ray structure of gallic acid, solvent effect on the structure and spectra. Vibrational Spectroscopy, 2007, vol. 43, no. 1, pp. 193–202. doi: 10.1016/j.vibspec.2006.07.008
18. Brandan S.A., Marquez Lopez F., Montejo M., Lopez Gonzalez J.J., Ben Altabef A. Theoretical and experimental vibrational spectrum study of 4-hydroxybenzoic acid as monomer and dimer. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 2010, vol. 75, no. 5, pp. 1422–1434. doi:10.1016/j.saa.2010.01.012
19. Trout C.C., Tambach T.J., Kubicki J.D. Correlation of observed and model vibrational frequencies for aqueous organic acids: UV resonance Raman spectra and molecular orbital calculations of benzoic, salicylic, and phthalic acids. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 2005, vol. 61, no. 11–12, pp. 2622–2633. doi: 10.1016/j.saa.2004.10.015
20. Course Notes on the Interpretation of Infrared and Raman Spectra. Eds. D.W. Mayo, F.A. Miller, R.W. Hannah. NJ, Wiley-Interscience, 2004, 567 p. doi: 10.1002/0471690082
