DOI: 10.17586/2226-1494-2019-19-2-374-376


HOLOGRAPHIC RECORDING IN PHOTOPOLYMERIZED NANOCOMPOSITE WITH DAST NANOCRYSTALS

T. N. Pogosian, I. Y. Denisyuk, I. Ledoux-Rak, Diep Lai Ngoc


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Pogosyan T.N., Denisyuk I.Yu., Ledoux-Rak Isabelle, Diep Lai Ngoc Holographic recording in photopolymerized nanocomposite with DAST nanocrystals. Scientific and Technical Journal of Information Technologies, Mechanics and Optics, 2019, vol. 19, no. 2,  pp. 374–376 (in Russian). doi: 10.17586/2226-1494-2019-19-2-374-376


Abstract

This paper is devoted to recording of a periodic lattice in the photopolymerized nanocomposite with nanoparticles of nonlinear optical DAST crystal (4-dimethylamino-N-methyl-4-stilbazolium tosylate) by holographic method. Nanocomposite consists of the mixture of two monomers: IDA (Isodecyl acrylate) and TMP (Trimethylolpropane ethoxylate (1 EO/OH) methyl ether diacrylate) with molecules of DAST dissolved in methanol. Initiator In2 (2,2-Dimethoxy-2-phenylacetophenone) provides photopolymerization.At solution centrifugal separation solvent evaporation and crystal formation start. It is shown that there is a record of the volume hologram when two-beam interference is used. Micro photos prove the movement of DAST nanoparticles in volume that provides creation of nonlinear grating, which can be used for quasi-phase matching of nonlinear effects.


Keywords: nanocomposite, nanoparticles, acrilate, holography, DAST, molecular crystals, nonlinear optics

Acknowledgements. This work was supported by the Russian Foundation for Basic Research RFBR (project No. 18-52-16014).

References
  1. Gleeson M.R., Sheridan J.T. A review of the modelling of free-radical photopolymerization in the formation of holographic gratings. Journal of Optics A: Pure and Applied Optics, 2009, vol. 11, no. 2, pp. 024008. doi: 10.1088/1464-4258/11/2/024008
  2. Suzuki N., Tomita Y., Kojima T. Holographic recording in TiO2 nanoparticle-dispersed methacrylate photopolymer films. Applied Physics Letters, 2002, vol. 81, no. 22, pp. 4121–4123. doi: 10.1063/1.1525391
  3. Pogosian T., Mai T.N.A., Denisyuk I., Lai N.D. Synthesis and nonlinear optics characterization of DAST submicron crystals in polymerized thin films. Micro-Structured and Specialty Optical Fibres V, 2018, vol. 10681. doi: 10.1117/12.2306686
  4. Burunkova J.A., Denisyuk I.Yu., Fokina M.I. Polymer composite based on DAST submicron crystals: technology and properties. Molecular Crystals and Liquid Crystals, 2014, vol. 589, pp. 178–182. doi: 10.1080/15421406.2013.872819
  5. Thomas T., Ramaclus J. V., Mena F. P., Mosquera E., Sagayaraja P., Michaelb E.A. Influence of oleic acid on the nucleation and growth of 4-N,N-dimethylamino-4-N-methyl-stilbazoliumtosylate (DAST) crystals. Cryst Eng Comm, 2015, vol. 17, no. 9, pp. 1989–1996. doi: 10.1039/c4ce02470b


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