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Editor-in-Chief
Nikiforov
Vladimir O.
D.Sc., Prof.
Partners
doi: 10.17586/2226-1494-2020-20-1-58-65
ENERGY CHARACTERISTICS OF CARBON-BASED COMPOSITE HEAT ELECTRIC STORAGE
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Article in Russian
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Abstract
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Ustinov A.S., Pitukhin E.A. Energy characteristics of carbon-based composite heat electric storage. Scientific and Technical Journal of Information Technologies, Mechanics and Optics, 2020, vol. 20, no. 1, pp. 58–65 (in Russian). doi: 10.17586/2226-1494-2020-20-1-58-65
Abstract
Subject of Research. The paper presents energy characteristics study of a carbon-containing composite material of a heat and power storage unit. We propose the composition and composite material technology for the heat and power storage unit. The initial components of the storage include graphite micro-powder, Na2O(SiO2)n water glass and a solidifier, Na2SiF6, sodium silicofluoride. The applicability of the developed heat and power storage unit is considered. Methods. The composition of composite material samples was studied by x-ray diffraction analysis and electron microscopy. Material characteristics were determined by thermophysical and electrophysical methods. Main Results. Samples of carbon-containing composite material are obtained. Engineering facilities of the heat and power storage unit are developed. Impedance frequency dependences of the heat electric storage unit experimental samples and their volt- ampere characteristics are obtained. The temperature dependences of electrical capacity and dielectric permittivity of the heat electric storage unit experimental samples are studied in the range of 20–60 °C. The temperature dependences of the specific heat capacity and the thermal conductivity coefficient for monotonous heating are obtained. Practical Relevance. The developed heat and power storage unit can be used in emergency lighting and heating systems and power supply when operating in the mode of constant or compensatory charging (private and administrative house construction). The developed material is applicable in temperature sensors.
Keywords: heat electric storage, electric and thermal energy, carbon, water glass, solid electrolyte, dielectric permittivity, impedance
References
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3. Du Pasquier A., Plitz I., Menocal S., Amatucci G. A comparative study of Li-ion battery, supercapacitor and nonaqueous asymmetric hybrid devices for automotive applications. Journal of Power Sources, 2003, vol. 115, no. 1, pp. 171–178. doi: 10.1016/S0378-7753(02)00718-8
4. Li H., Cheng L., Xia Y. A hybrid electrochemical supercapacitor based on a 5 V Li-ion battery cathode and active carbon. Electrochemical and Solid State Letters, 2005, vol. 8, no. 9, pp. A433–A436. doi: 10.1149/1.1960007
5. Du C., Yeh J., Pan N. High power density supercapacitors using locally aligned carbon nanotube electrodes. Nanotechnology, 2005, vol. 16, no. 4, pp. 350–353. doi: 10.1088/0957-4484/16/4/003
6. Emmenegger Ch., Mauron Ph., Sudan P., Wenger P., Hermann V., Gallay R., Züttel A. Investigation of electrochemical double-layer (ECDL) capacitors electrodes based on carbon nanotubes and activated carbon materials. Journal of Power Sources, 2003, vol. 124, no. 1, pp. 321–329. doi: 10.1016/S0378-7753(03)00590-1
7. He Y.M., Chen W.J., Li X.D., Zhang Z.X., Fu J.C., Zhao C.H., Xie E.Q. Freestanding three-dimensional graphene/MnO2 composite networks as ultralight and flexible supercapacitor electrodes. ACS Nano, 2013, vol. 7, no. 1, pp. 174–182. doi: 10.1021/nn304833s
8. Brandhorst H.W.,Jr, Chen Z. Achieving a high pulse power system through engineering the battery-capacitor combination. Proc. 16th Annual Battery Conference on Applications and Advances, 2001, pp. 153–156. doi: 10.1109/BCAA.2001.905115
9. Gao L., Dougal R., Liu S. Power enhancement of an actively controlled battery/ultracapacitor hybrid. IEEE Transactions on Power Electronics, 2005, vol. 20, no. 1, pp. 236–243. doi: 10.1109/TPEL.2004.839784
10. Leedy A.W., Nelms R.M. Analysis of a capacitor-based hybrid source used for pulsed load applications. Proc. 37th Intersociety Energy Conversion Engineering Conference, 2002, pp. 1–6.
11. Grekova A., Gordeeva L., Aristov Y. Composite sorbents «Li/Ca halogenides inside Multi-wall Carbon Nano-tubes» for Thermal Energy Storage. Solar Energy Materials and Solar Cells, 2016, vol. 155, pp. 176–183. doi: 10.1016/j.solmat.2016.06.006
12. Shekhmeister E.I., Vasserman R.N., Maizel L.S. Techno-Chemical Actions in Electron-Vacuum Manufacturing. Tutorial. Moscow, Vysshaja shkola Publ., 1967, 352 p. (in Russian)
13. Pitukhin E.A., Ustinov A.S. Fire-resistance properties research of “water glass - graphite microparticles” composite material. Scientific and Technical Journal of Information Technologies, Mechanics and Optics, 2016, vol. 16, no. 2, pp. 277–283. (in Russian). doi: 10.17586/2226-1494-2016-16-2-277-283
14. Ustinov A.S., Pitukhin E.A. Research of “water glass — graphite microparticles” composite material by thermogravimetry method. Scientific and Technical Journal of Information Technologies, Mechanics and Optics, 2017, vol. 17, no. 5, pp. 826–833. (in Russian). doi: 10.17586/2226-1494-2017-17-5-826-833
15. Gostev V.A., Pituhin E.A., Ustinov A.S., Yakovleva D.A. Thermal insulation properties research of the composite material water glass- graphite microparticles. Scientific and Technical Journal of Information Technologies, Mechanics and Optics, 2014, no. 3(91). pp. 81–87. (in Russian)
16. Ustinov A.S., Rogozin S.S., Pitukhin E.A. Development and implementation of a mathematical model of the thermal effect on enclosing structures covered with fire-retardant composite material. Systems. Methods. Technologies, 2018, no. 3(39), pp. 41–48. (in Russian). doi: 10.18324/2077-5415-2018-3-41-48
17. Ustinov A.S. Application method of fire-retardant composite material “water glass-graphite microparticles” on enclosure surface. Scientific and Technical Journal of Information Technologies, Mechanics and Optics, 2018, vol. 18, no. 6, pp. 1001–1007. (in Russian). doi: 10.17586/2226-1494-2018-18-6-1001-1007
18. Nemtcov M.V., Nemtcov M.L. Electrical Engineering and Electronics. Tutorial. Moscow, Akademija Publ., 2007, 432 p. (in Russian)
19. Krohns S., Lunkenheimer P., Kant Ch., Pronin A.V., Brom H.B., Nugroho A.A., Diantoro M., Loidl A. Colossal dielectric constant up to gigahertz at room temperature. Applied Physics Letters, 2009, vol. 94, no. 12, pp. 122903. doi: 10.1063/1.3105993
References
1. Kim H., Popov B.N. A mathematical model of oxide/carbon composite electrode for supercapacitors. Journal of the Electrochemical Society, 2003, vol. 150, no. 9, pp. A1153–A1160. doi: 10.1149/1.1593039
2. Kim I.H., Kim J.H., Kim K.B. Electrochemical characterization of electrochemically prepared ruthenium oxide/carbon nanotube electrode for supercapacitor application. Electrochemical and Solid State Letters, 2005, vol. 8, no. 7, pp. A369–A372. doi: 10.1149/1.1925067
3. Du Pasquier A., Plitz I., Menocal S., Amatucci G. A comparative study of Li-ion battery, supercapacitor and nonaqueous asymmetric hybrid devices for automotive applications. Journal of Power Sources, 2003, vol. 115, no. 1, pp. 171–178. doi: 10.1016/S0378-7753(02)00718-8
4. Li H., Cheng L., Xia Y. A hybrid electrochemical supercapacitor based on a 5 V Li-ion battery cathode and active carbon. Electrochemical and Solid State Letters, 2005, vol. 8, no. 9, pp. A433–A436. doi: 10.1149/1.1960007
5. Du C., Yeh J., Pan N. High power density supercapacitors using locally aligned carbon nanotube electrodes. Nanotechnology, 2005, vol. 16, no. 4, pp. 350–353. doi: 10.1088/0957-4484/16/4/003
6. Emmenegger Ch., Mauron Ph., Sudan P., Wenger P., Hermann V., Gallay R., Züttel A. Investigation of electrochemical double-layer (ECDL) capacitors electrodes based on carbon nanotubes and activated carbon materials. Journal of Power Sources, 2003, vol. 124, no. 1, pp. 321–329. doi: 10.1016/S0378-7753(03)00590-1
7. He Y.M., Chen W.J., Li X.D., Zhang Z.X., Fu J.C., Zhao C.H., Xie E.Q. Freestanding three-dimensional graphene/MnO2 composite networks as ultralight and flexible supercapacitor electrodes. ACS Nano, 2013, vol. 7, no. 1, pp. 174–182. doi: 10.1021/nn304833s
8. Brandhorst H.W.,Jr, Chen Z. Achieving a high pulse power system through engineering the battery-capacitor combination. Proc. 16th Annual Battery Conference on Applications and Advances, 2001, pp. 153–156. doi: 10.1109/BCAA.2001.905115
9. Gao L., Dougal R., Liu S. Power enhancement of an actively controlled battery/ultracapacitor hybrid. IEEE Transactions on Power Electronics, 2005, vol. 20, no. 1, pp. 236–243. doi: 10.1109/TPEL.2004.839784
10. Leedy A.W., Nelms R.M. Analysis of a capacitor-based hybrid source used for pulsed load applications. Proc. 37th Intersociety Energy Conversion Engineering Conference, 2002, pp. 1–6.
11. Grekova A., Gordeeva L., Aristov Y. Composite sorbents «Li/Ca halogenides inside Multi-wall Carbon Nano-tubes» for Thermal Energy Storage. Solar Energy Materials and Solar Cells, 2016, vol. 155, pp. 176–183. doi: 10.1016/j.solmat.2016.06.006
12. Shekhmeister E.I., Vasserman R.N., Maizel L.S. Techno-Chemical Actions in Electron-Vacuum Manufacturing. Tutorial. Moscow, Vysshaja shkola Publ., 1967, 352 p. (in Russian)
13. Pitukhin E.A., Ustinov A.S. Fire-resistance properties research of “water glass - graphite microparticles” composite material. Scientific and Technical Journal of Information Technologies, Mechanics and Optics, 2016, vol. 16, no. 2, pp. 277–283. (in Russian). doi: 10.17586/2226-1494-2016-16-2-277-283
14. Ustinov A.S., Pitukhin E.A. Research of “water glass — graphite microparticles” composite material by thermogravimetry method. Scientific and Technical Journal of Information Technologies, Mechanics and Optics, 2017, vol. 17, no. 5, pp. 826–833. (in Russian). doi: 10.17586/2226-1494-2017-17-5-826-833
15. Gostev V.A., Pituhin E.A., Ustinov A.S., Yakovleva D.A. Thermal insulation properties research of the composite material water glass- graphite microparticles. Scientific and Technical Journal of Information Technologies, Mechanics and Optics, 2014, no. 3(91). pp. 81–87. (in Russian)
16. Ustinov A.S., Rogozin S.S., Pitukhin E.A. Development and implementation of a mathematical model of the thermal effect on enclosing structures covered with fire-retardant composite material. Systems. Methods. Technologies, 2018, no. 3(39), pp. 41–48. (in Russian). doi: 10.18324/2077-5415-2018-3-41-48
17. Ustinov A.S. Application method of fire-retardant composite material “water glass-graphite microparticles” on enclosure surface. Scientific and Technical Journal of Information Technologies, Mechanics and Optics, 2018, vol. 18, no. 6, pp. 1001–1007. (in Russian). doi: 10.17586/2226-1494-2018-18-6-1001-1007
18. Nemtcov M.V., Nemtcov M.L. Electrical Engineering and Electronics. Tutorial. Moscow, Akademija Publ., 2007, 432 p. (in Russian)
19. Krohns S., Lunkenheimer P., Kant Ch., Pronin A.V., Brom H.B., Nugroho A.A., Diantoro M., Loidl A. Colossal dielectric constant up to gigahertz at room temperature. Applied Physics Letters, 2009, vol. 94, no. 12, pp. 122903. doi: 10.1063/1.3105993