doi: 10.17586/2226-1494-2022-22-1-10-17


Optical composites based on organic polymers and semiconductor pigments

V. M. Volynkin, S. K. Evstropiev, D. V. Bulyga, A. V. Morkovsky, S. S. Pashin, K. V. Dukelskiy, A. V. Bourdine, I. B. Bondarenko


Read the full article  ';
Article in Russian

For citation:
Volynkin V.M., Evstropiev S.K., Bulyga D.V., Morkovsky A.V., Pashin S.S., Dukelsky K.V., Burdin A.V., Bondarenko I.B. Optical composites based on organic polymers and semiconductor pigments. Scientific and Technical Journal of Information Technologies, Mechanics and Optics, 2022, vol. 22, no. 1, pp. 10–17 (in Russian). doi: 10.17586/2226-1494-2022-22-1-10-17


Abstract
The aim of the work was the development of optical organic-inorganic composite materials with high absorption of light the visible part of the spectrum and high reflection in the near infrared region of the spectrum. Such materials are used in industry and construction as coatings. To create these optical composites, epoxy and epoxy-polyurethane polymer matrices containing inorganic semiconducting particles (CuS, PbS, Fe3O4) were used. Highly dispersive powders of inorganic pigments were used for the preparation of homogeneous composite materials. The wet precipitation method with the application of organic stabilizing additions was applied for the preparation of dispersive CuS and PbS powders. Optical microscopy and X-ray diffraction analysis helped to study the crystal structure and morphology of the obtained semiconductor pigments. PMT-3 device was applied for microhardness measurements of the prepared composite materials. Based on the data of X-ray diffraction analysis, the average crystallite size was calculated using the Scherrer formula. It was found that freshly precipitated CuS and PbS powders consist of nanocrystals with a size of 11–20 nm. Optical microscopy data indicate the formation of aggregates of semiconductor nanocrystals in powders. Experiments have shown that all synthesized composites have low light reflection coefficient (less than 0.06) in the visible part of the spectrum and an increased light reflection coefficient in the near infrared region of the spectrum (0.13–0.15 and more). The results of the study showed that the use of epoxy-polyurethane polymer matrices provides greater microhardness of composite materials, compared to the composites based on epoxy polymers. The highest microhardness values were observed in composite materials based on epoxy-polyurethane polymers containing highly dispersed Fe3O4 particles. Obtained organic-inorganic composites could be used as materials for light-absorbing coatings in different industrial applications.

Keywords: epoxy polymer, polyurethane, PbS, CuS, magnetite

References
  1. Takeda H., Yabuki K. Visible light absorbing film, structural member having this visible light absorbing film and visible light absorbing ink which forms visible light absorbing film. Patent US7927696B2, 2011.
  2. Qin J., Qu J., Song J.R., Song Z.N., Zhang W.D., Shi Y.X., Zhang T., Xue X., Zhang R.P., Zhang H.Q., Zhang Z.Y., Wu X. The optical properties of black coatings and their estimated cooling effect and cooling energy savings potential. Journal of Power and Energy Engineering, 2014, vol. 2, pp. 68–75. http://dx.doi.org/10.4236/jpee.2014.24011
  3. Gershbejn A.M. Method for production of image and printing ink for realization of this method (modifications). Patent RU 2244631 С2, 2005. (in Russian)
  4. Sanada K. Infrared reflecting black pigment, coating material and resin composition. Patent EP 1847512 A1, 2006.
  5. Martinkevich A.A., Prokopchuk N.R. Pigments for Modern Paints and Varnishes. Minsk, BSTU Publ., 2014, 130 p. (in Russian)
  6. Fang V., Kenedy J., Futter J., Manning J. A review of infrared reflectance properties of metal oxide nanostructures. GNS Science Report 2013/39, 23 p.
  7. VolynkinV.M., KiselevV.M., EvstropevS.K., BurchinovA.N., MatveentsevA.V. Light-absorbing coating. Patent RU 2626838 C2, 2017. (in Russian)
  8. Kiselev V.M., Burchinov A.A., Volynkin V.M., Evstropev S.K., Matveentsev A.V., Composite light-absorbent coatings based on hollow oxide microspheres and lead sulfide. Journal of Optical Technology, 2015, vol. 82, no. 12, pp. 824–826. https://doi.org/10.1364/JOT.82.000824
  9. Graighead H.G., Howard R.E. Light-absorbing materials. Patent US 4284689 A, 1981.
  10. Samsonov K.N. Light-absorbing coating. Patent RU 126149 U1, 2013. (in Russian)
  11. Nabiyouni G., Moghimi E., Hedayati K., Jalajerdi R. Room temperature synthesis of lead sulfide nanoparticles. Main Group Metal Chemistry, 2012, vol. 35, no. 5-6, pp. 173–178. https://doi.org/10.1515/mgmc-2012-0036
  12. Chongad L.S., Sharma A., Banerjee M., Jain A. Synthesis of lead sulfide nanoparticles by chemical precipitation method. Journal of Physics: Conference Series, 2016, vol. 755, pp. 012032. https://doi.org/10.1088/1742-6596/755/1/012032
  13. Evstropiev S.K., Kislyakov I.M., Bagrov I.V., Belousova I.M. Stabilization of PbS quantum dots by high molecular polyvinylpyrrolidone. Polymers for Advanced Technology, 2016, vol. 27, no. 3, pp. 314–317. https://doi.org/10.1002/pat.3642
  14. Lu S., Sohling U., Krajewski T., Mennig M., Schmidt H.K. Synthesis and characterization of PbS nanoparticles in ethanolic solution stabilized by hydroxypropyl cellulose. Journal of Materials Science Letters, 1998, vol. 17, no. 24, pp. 2071–2073. https://doi.org/10.1023/A:1006671814597
  15. Huang Z., Zhai G., Zhang Z., Zhang C., Xia Y., Lian L., Fu X., Zhang D., Zhang J. Low cost and large scale synthesis of PbS quantum dots with hybrid surface passivation. CrystEngComm, 2017, vol. 19, no. 6, pp. 946–951. https://doi.org/10.1039/C6CE02471H
  16. Bagrov I.A., Danilov V.V., Evstrop’ev S.K., Kiselev V.M., Kislyakov I.M., Panfutova A.S., Khrebtov A.I. Photoinduced variation of the luminescent properties of PbS nanoparticle suspensions stabilized by polyvinylpyrrolidone. Technical Physics Letters, 2015, vol. 41, no. 1, pp. 65–68. https://doi.org/10.1134/S1063785015010198
  17. Jiao Y., Gao X., Lu J., Chen Y., Zhou J., Li X. A novel method for PbS quantum dot synthesis. Materials Letters, 2012, vol. 72, pp. 116–118. https://doi.org/10.1016/j.matlet.2011.12.068
  18. Fu H., Tsang S.-W., Zhang Y., Ouyang J., Lu J., Yu K., Tao Y. Impact of the growth conditions of colloidal PbS nanocrystals on photovoltaic device performance. Chemistry of Materials, 2011, vol. 23, no. 7, pp. 1805–1810. https://doi.org/10.1021/cm200051j
  19. Shyju T.S., Anandhi S., Sivakumar R., Gopalakrishnan R. Studies on lead sulfide (PbS) semiconducting thin films deposited from nanoparticles and its NLO application. International Journal of Nanoscience,2014, vol. 13, no. 1, pp. 1450001. https://doi.org/10.1142/S0219581X1450001X
  20. Chursova L.V., Panina N.N., Grebeneva T.A., Kutergina I.Iu. Epoxy Resins, Hardeners, Densifiers and Binders Based on Them. St. Petersburg, Professija Publ., 2020, 576 p. (in Russian)
  21. Sang J.J., Kohli D.K., Shah K.G. Structural adhesive and bonding application thereof. Patent USA 8974905 B2, 2015.
  22. Kulagina A.S., Sandulenko A.V., Volynkin V.M., Evstropiev S.K. Synthesis and nonlinear optical properties of vanadium-doped plasticized epoxy polymer composites. Advanced Composites and Hybrid Materials, 2021, vol. 4, no. 2, pp. 324–331. https://doi.org/10.1007/s42114-021-00227-y
  23. Belousova I.M., Videnichev D.A., Volynkin V.M., Evstropiev S.K., Kislyakov I.M., Murav’ova T.D., Rakov E.G. Nonlinear optical limiters of pulsed laser radiation based on carbon-containing nanostructures in viscous and solid matrices. Polymers for Advanced Technologies, 2014, vol. 25, no. 9, pp. 1008–1013. https://doi.org/10.1002/pat.3343
  24. Natsik V.D., Fomenko L.S., Lubenets S.V. Investigation of the creep and glass transition of elastomers by the microindentation method: epoxy resin and related nanocomposites. Physics of the Solid State, 2013, vol. 55, no. 5, pp. 1020–1033. https://doi.org/10.1134/S1063783413050260
  25. Low I.M., Shi C. Vickers indentation responses of epoxy polymers. Journal of Materials Science Letters, 1998, vol. 17, no. 14, pp. 1181–1183. https://doi.org/10.1023/A:1006517005082


Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License
Copyright 2001-2024 ©
Scientific and Technical Journal
of Information Technologies, Mechanics and Optics.
All rights reserved.

Яндекс.Метрика