doi: 10.17586/2226-1494-2022-22-6-1078-1084


Luminescence technique for studying the growth of AgInS2 quantum dots

A. K. Ahmad, A. H. Mohammed, A. A. Skaptsov


Read the full article  ';
Article in English

For citation:
Ahmad A.K., Mohammed A.H., Skaptsov A.A. Luminescence technique for studying the growth of AgInS2 quantum dots. Scientific and Technical Journal of Information Technologies, Mechanics and Optics, 2022, vol. 22, no. 6, pp. 1078–1084. doi: 10.17586/2226-1494-2022-22-6-1078-1084


Abstract
Although nanoparticle production techniques are well-known, getting nanoparticles with specific characteristics that enable their application as biosensors is an entirely other problem. Many issues occur as a result of employing the method for producing repeatable and time-stable nanostructures. We created AgInS2 nanoparticles as colloidal quantum dots in a variety of methods to test the efficiency of the synthesis process on the optical characteristics of the nanoparticles, as well as their size, composition, absorption, and luminescence spectra. The capillary electrophoresis (CE) approach for AgInS2 production was employed, with modifications in solvent and temperature, to get nanocrystal (NC) particles. The researchers discovered that Ag accumulation in the InS lattice promotes deformation which leads to structural defects. Consequently, the direction of a nanoparticle light band may now be changed. The features of mixed AgInS2 nanoparticles have been examined with respect to different fabrication procedures, surface stability, and metal impurity incorporation. One band dominates in the luminescence spectra of AgxIn1–xS2 nanoparticles. The relationship between the stoichiometric ratio, luminescence amplitude, line width, and the maximum wavelength is investigated. The average size of the received nanocrystals was determined using dynamic light scattering studies. The computed nanoparticle diameter range has an average particle size of 3–3.5 nm.

Keywords: AgInS2, quantum dot, luminescence, synthesis of nanocrystalline particles, biosensors

References
  1. Du W.M., Qian X.F., Yin J., Gong Q. Shape- and phase-controlled synthesis of monodisperse, single-crystalline ternary chalcogenide colloids through a convenient solution synthesis strategy. Chemistry - A European Journal, 2007, vol. 13, no. 31, pp. 8840–8846. https://doi.org/10.1002/chem.200700618
  2. Ogawa T., Kuzuya T., Hamanaka Y., Sumiyama K.J. Synthesis of Ag–In binary sulfide nanoparticles—structural tuning and their photoluminescence properties. Journal of Materials Chemistry, 2010, vol. 20, no. 11, pp. 2226–2231. https://doi.org/10.1039/B920732E
  3. Torimoto T., Adachi T., Okazaki K., Sakuraoka M., Shibayama T., Ohtani B., Kudo A., Kuwabata S. Facile synthesis of ZnS−AglnS2 solid solution nanoparticles for a color-adjustable luminophore. Journal of the American Chemical Society, 2007, vol. 129, no. 41, pp. 12388–12389. https://doi.org/10.1021/ja0750470
  4. Wang D.S., Zheng W., Hao C.H., Peng Q., Li Y. General synthesis of I–III–VI2 ternary semiconductor nanocrystals. Chemical Communications, 2008, vol. 22, pp. 2556–2558. https://doi.org/10.1039/B800726H
  5. Xie R.G., Rutherford M., Peng X.G. Formation of high-quality I−III−VI semiconductor nanocrystals by tuning relative reactivity of cationic precursors. Journal of the American Chemical Society, 2009, vol. 131, no. 15, pp. 5691–5697. https://doi.org/10.1021/ja9005767
  6. Feng Z.Y., Dai P.C., Ma X.C., Zhan J.H., Lin Z. Monodispersed cation-disordered cubic AgInS2 nanocrystals with enhanced fluorescence. Applied Physics Letters, 2010, vol. 96, no. 1, pp. 013104.   https://doi.org/10.1063/1.3280372
  7. Chopra K.L., Das S.R. Thin Film Solar Cells. New York; London, 1983.
  8. Alkhasov A.B.Renewable Energy.Moscow, Fizmatlit Publ., 2010. 255 p. (in Russian)
  9. Ariezo M., Loferski J.J. Investigation of potentially high efficiency photovoltaic cells consisting of two heterojunctions on a common wide band gap semiconductor base. Proc. of the 13th IEEE Photovoltaic Specialists Conference, 1978,pp. 898–903.
  10. Abdullaev M.A., Alhasov A.B., Magomedova D.Kh. Fabrication and properties of CuInSe2/AgInSe2/CdS double heterojunction cascade solar cells.Inorganic Materials, 2014, vol. 50, no. 3, pp. 228–232. https://doi.org/10.1134/S0020168514030017
  11. Maestro L.M., Rodríguez E.M., Rodríguez F.S., Iglesias-de la Cruz M.C., Juarranz A., Naccache R., Vetrone F., Jaque D., Capobianco J.A., Solé J.G. CdSe quantum dots for two-photon fluorescence thermal imaging. Nano Letters, 2010, vol. 10, no. 12, pp. 5109–5115. https://doi.org/10.1021/nl1036098
  12. YangJ.M., YangH., LinL. Quantum dot nano thermometers reveal heterogeneous local thermogenesis in living cells. ACSNano, 2011, vol. 5,no. 6, pp. 5067–5071. https://doi.org/10.1021/nn201142f
  13. Skaptsov A.A., Ustalkov S.O., Mohammed A.H., Savenko O.A., Novikova A.S., Kozlova E.A., Kochubey V.I. Fabrication and characterization of biological tissue phantoms with embedded nanoparticles. Journal of Physics: Conference Series, 2017, vol. 917, no. 4, pp. 042003. https://doi.org/10.1088/1742-6596/917/4/042003
  14. Ustalkov S.O., Kozlova E.A., Savenko O.A., Mohammed A.H., Kochubey V.I., Skaptsov A.A. Influence of excitation power density on temperature dependencies of NAYF4:Yb, Er nanoparticles luminescence spectra. Proceedings of SPIE, 2017, vol. 10336, pp. 1033614. https://doi.org/10.1117/12.2269297
  15. Jensen R.A.Optical studies of colloidal quantum dots: optical trapping with plasmonic nano apertures and thermal recovery from photoinduced dimming.PhD thesis.Department of Chemistry, Massachusetts Institute of Technology,2015.
  16. Booth M. Synthesis and characterisation of CuInS2 quantum dots. PhD thesis. The University of Leeds School of Physics & Astronomy, 2014.
  17. Peng X., Wickham J., Alivisatos A.P. Kinetics of II-VI and III-V colloidal semiconductor nanocrystal growth: “focusing” of size distributions. Journal of the American Chemical Society, 1998, vol. 120, no. 21, pp. 5343–5344. https://doi.org/10.1021/ja9805425
  18. Mohmmed A.H., Skaptsov A.A., Ahmad A.K. Luminescence method to characterize the synthesis of ZnCdS quantum dots in real time. Materials Today: Proceedings, 2021, vol. 42, pp. 2803–2807.https://doi.org/10.1016/j.matpr.2020.12.725
  19. Kochubey V.I., Konyukhova Ju.G., Volkova E.K. Effect of polyacrylic acid shell on luminescence and phosphorescence of ZnCdS nanoparticles. Book of Abstracts of the 3rd International Symposium “Molecular photonics”, St. Petersburg, Russia, VVM Publishing Ltd, 2012, pp. 137.
  20. VolkovaE.K., Kochubeĭ V.I. Synthesis and luminescent characteristics of CdS nanoparticles. International Symposium "Nanophotonics-2011": Сollection of the reports abstracts and programs. Ukraine, Crimea, 2011, pp. 1–2. (in Russian)
  21. Volkova E.K., Yanina I.Yu., Sagaydachnaya E., Konyukhova J.G., Kochubey V.I., TuchinV.V. Effect of luminescence transport through adipose tissue on measurement of tissue temperature bY using ZnCdS nanothermometers. Proceedings of SPIE, 2018, vol. 10493, pp. 104931K. https://doi.org/10.1117/12.2295620


Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License
Copyright 2001-2024 ©
Scientific and Technical Journal
of Information Technologies, Mechanics and Optics.
All rights reserved.

Яндекс.Метрика