doi: 10.17586/2226-1494-2023-23-1-1-13


Characterization of the holographic photopolymer Bayfol HX in the IR region

V. N. Borisov, A. D. Zverev, V. A. Kamynin, M. S. Kopyeva, R. A. Okun, V. B. Tsvetkov


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Borisov V.N., Zverev A.D., Kamynin V.A., Kopyeva M.S., Okun R.A., Tsvetkov V.B. Characterization of the holographic photopolymer Bayfol HX in the IR region. Scientific and Technical Journal of Information Technologies, Mechanics and Optics, 2023, vol. 23, no. 1, pp. 1–13 (in Russian). doi: 10.17586/2226-1494-2023-23-1-1-13


Abstract
The possibility of creating holographic optical elements operating in the near infrared spectral range based on the Bayfol HX holographic photopolymer has been considered. The dynamic range of the refractive index of the photopolymer and the amplitude-phase nature of the holograms in the infrared range have been studied. The influence of recording parameters (power density of recording radiation, recording time) on the distribution of the dynamic range of the refractive index between grating harmonics has been studied. The analysis of the amplitude-phase nature of holograms was carried out by measuring the transmission spectra of the studied photopolymer after the photopolymerization reaction. The dynamic range of the refractive index of a photopolymer evaluated in the spectral range from 405 nm to 2099 nm. For this purpose, the angular selectivity contours of holograms with periods from 414 nm to 2100 nm, optimized for different parts of the specified spectral range, were measured and analyzed. The influence of recording parameters on the distribution of the dynamic range of the refractive index between the grating harmonics was analyzed by calculating the amplitudes of the first and second harmonics of the refractive index modulation from the experimentally measured angular selectivity contours of holograms recorded with different recording time at a constant irradiation dose. It was shown that the dynamic range of the refractive index of the photopolymer in the near infrared spectral range, as compared with the long-wavelength part of the visible region of the spectrum, differs by a value that does not exceed the measurement accuracy. A pronounced violation of the reciprocity was demonstrated with scaling of the interference pattern or with changing of the power density of the recording radiation. The optimal recording conditions for holograms calculated for the infrared spectral range for the studied photopolymer were found. The possibility of using of the studied holographic material in telecommunication optics has been demonstrated.

Keywords: holography, Bayfol, photopolymer, IR radiation, diffractive optics

Acknowledgements. This research was funded with the financial support of the Ministry of Science and Higher Education of the Russian Federation, grant number 075-15-2020-912, and carried out on the basis of the World-Class Research Center “Photonics”. The authors thank Dr. Friedrich-Karl Bruder for providing the Bayfol HX holographic medium, and Lesnichii Vasilii Valerievich for consultations on the analysis of experimental results.

References
  1. Quintana J.A., Boj P.G., Crespo J., Pardo M., Satorre M.A. Line-focusing holographic mirrors for solar ultraviolet energy concentration. Applied Optics, 1997, vol. 36, no. 16, pp. 3689–3693.https://doi.org/10.1364/AO.36.003689
  2. Glebov L.B., Smirnov V., Rotari E., Cohanoschi I., Glebova L., Smolski O.V., Lumeau J., Lantigua C., Glebov A. Volume-chirped Bragg gratings: monolithic components for stretching and compression of ultrashort laser pulses. Optical Engineering, 2014, vol. 53, no. 5, pp. 051514.https://doi.org/10.1117/1.OE.53.5.051514
  3. Berneth H., Bruder F.-K., Fäcke T., Hagen R., Hönel D., Jurbergs D., Rölle T., Weiser M.-S. Holographic recording aspects of high-resolution Bayfol HX photopolymer. Proceedings ofSPIE,2011, vol. 7957, pp. 79570H.https://doi.org/10.1117/12.876202
  4. Bruder F.-K., Hansen S., Kleinschmidt T., Künzel R., Manecke C., Orselli E., Rewitz C., Rölle T. Integration of volume holographic optical elements (vHOE) made with Bayfol® HX into plastic optical parts. Proceedings ofSPIE,2019,vol. 10944, pp. 1094402.https://doi.org/10.1117/12.2510109
  5. Vázquez-Martín I., Gómez-Climente M., Marín-Sáez J., Collados M.V., Atencia J. True colour Denisyuk-type hologram recording in Bayfol HX self-developing photopolymer. Proceedings ofSPIE, 2017, vol. 10233, pp. 102331U.https://doi.org/10.1117/12.2265802
  6. Marín-Sáez J., Atencia J., Chemisana D., Collados M.V. Full modeling and experimental validation of cylindrical holographic lenses recorded in Bayfol HX photopolymer and partly operating in the transition regime for solar concentration. Optics Express, 2018, vol. 26, no. 10, pp. A398–A412.https://doi.org/10.1364/OE.26.00A398
  7. Bruder F.-K., Fäcke T., Grote F., Hagen R., Hönel D., Koch E., Rewitz C., Walze G., Wewer B. Performance optimization in mass production of volume holographic optical elements (vHOEs) using Bayfol HX photopolymer film. Proceedings ofSPIE,2017,vol. 10233,pp. 102330G.https://doi.org/10.1117/12.2265022
  8. Berneth H., Bruder F.-K., Fäcke T., Jurbergs D., Hagen R., Hönel D., Rölle T., Walze G. Bayfol HX photopolymer for full-color transmission volume Bragg gratings. Proceedings ofSPIE,2014, vol. 9006,pp. 900602.https://doi.org/10.1117/12.2038399
  9. Bruder F.-K., Fäcke T., Hagen R., Hönel D., Orselli E., Rewitz C., Rölle T., Walze G. Diffractive optics with high Bragg selectivity: volume holographic optical elements in Bayfol® HX photopolymer film. Proceedings ofSPIE,2015,vol. 9626,pp. 96260T.https://doi.org/10.1117/12.2191587
  10. Bruder F.-K., Bang H., Fäcke T., Hagen R., Hönel D., Orselli E., Rewitz C., Rölle T., Vukicevic D., Walze G. Precision holographic optical elements in Bayfol HX photopolymer. Proceedings ofSPIE,2016,vol. 9771,pp. 977103.https://doi.org/10.1117/12.2209636
  11. Bruder F.-K., Fäcke T., Hagen R., Hönel D., Kleinschmidt T.P., Orselli E., Rewitz C., Rölle T., Walze G. Diffractive optics in large sizes: computer-generated holograms (CGH) based on Bayfol HX photopolymer. Proceedings ofSPIE,2015, vol. 9385,pp. 93850C.https://doi.org/10.1117/12.2077139
  12. Marín-Sáez J., Atencia J., Chemisana D., Collados M.V. Characterization of volume holographic optical elements recorded in Bayfol HX photopolymer for solar photovoltaic applications. Optics Express, 2016, vol. 24, no. 6, pp. A720–A730.https://doi.org/10.1364/OE.24.00A720
  13. Bruder F.-K., Frank J., Hansen S., Lorenz A., Manecke C., Meisenheimer R., Mills J., Pitzer L., Pochorovski I., Rölle T. Expanding the property profile of Bayfol HX filmstowards NIR recording and ultra-high index modulation. Proceedings ofSPIE,2021, vol. 11765,pp. 117650J.https://doi.org/10.1117/12.2579235
  14. PengH., NairD.P.,KowalskiB.A., XiW., GongT., WangC., ColeM., CramerN.B., XieX., McLeodR.R., BowmanC.N. High performance graded rainbow holograms via two-stage sequential orthogonal thiol–click chemistry.Macromolecules,2014, vol. 47, no. 7, pp. 2306–2315. https://doi.org/10.1021/ma500167x
  15. Monte F.D., Martínez O., Rodrigo J. A., Calvo M. L., Cheben P. A volume holographic sol-gel material with large enhancement of dynamic range by incorporation of high refractive index species. Advanced Materials, 2006, vol. 18, no. 15, pp. 2014–2017.https://doi.org/10.1002/adma.200502675
  16. Bruder F.-K., Fäcke T., Rölle T. The chemistry and physics of Bayfol® HX film holographic photopolymer. Polymers, 2017, vol. 9, no. 10, pp. 472.https://doi.org/10.3390/polym9100472
  17. Kargaran A., Ebrahimi M., Riazi M., Hosseiny A., Jafari G.R. Quartic balance theory: Global minimum with imbalanced triangles. Physical Review, 2020, vol. 102, no. 1, pp. 012310.https://doi.org/10.1103/PhysRevE.102.012310
  18. Spiegler K.S., Kedem O. Thermodynamics of hyperfiltration (reverse osmosis): criteria for efficient membranes. Desalination, 1966, vol. 1, no. 4, pp. 311–326.https://doi.org/10.1016/S0011-9164(00)80018-1
  19. Lucarini V., Saarinen J.J., Peiponen K.-E., Vartiainen E.M. Kramers-Kronig Relations in Optical Materials Research. Springer Science & Business Media,2005. 162 p.Springer Series in Optical Sciences, vol. 110. https://doi.org/10.1007/b138913
  20. Kopyeva M.S., Filatova S.A., Kamynin V.A., Trikshev A.I., Kozlikina E.I., Astashov V.V., Loschenov V.B., Tsvetkov V.B. Ex-vivo exposure on biological tissues in the 2-μm spectral range with an all-fiber continuous-wave holmium laser. Photonics, 2021,vol. 9, no. 1, pp. 20. https://doi.org/10.3390/photonics9010020
  21. Kogelnik H. Coupled wave theory for thick hologram gratings. Bell System Technical Journal, 1969, vol. 48, no. 9, pp. 2909–2947.https://doi.org/10.1002/j.1538-7305.1969.tb01198.x
  22. Borisov V.N., Angervaks A.E., Ryskin A.I., Veniaminov A.V. Two-model spectral study of volume holograms in materials with diffusion-based mechanisms. Optical Engineering, 2019, vol. 58, no. 2, pp. 024102.https://doi.org/10.1117/1.OE.58.2.024102
  23. Mees E.K., James T.H. The Theory of the Photographic Process. New York, Macmillan, 1967, chap. 7, pp. 132.
  24. Pottier P., Strain M.J., Packirisamy M. Integrated microspectrometer with ellipticalBragg mirror enhanced diffraction grating on silicon on insulator.ACS Photonics, 2014, vol. 1,no. 5, pp. 430−436. https://doi.org/10.1021/ph400165j
  25. Liu P., Zhao Y., Li Z., Sun X. Improvement of ultrafast holographic performance in silver nanoprisms dispersed photopolymer. Optics Express, 2018, vol. 26, no. 6, pp. 6993–7004.https://doi.org/10.1364/OE.26.006993
  26. Sheridan J.T., Lawrence J.R. Nonlocal-response diffusion model of holographic recording in photopolymer. Journal of the Optical Society of America A, 2000, vol. 17, no. 6, pp. 1108–1114.https://doi.org/10.1364/JOSAA.17.001108
  27. Zhao G., Mouroulis P. Diffusion model of hologram formation in dry photopolymer materials. Journal of Modern Optics, 1994, vol. 41, no. 10, pp. 1929–1939.https://doi.org/10.1080/09500349414551831
  28. Kelly J.V., O'Neill F.T., Sheridan J.T., Neipp C., Gallego S., Ortuno M. Holographic photopolymer materials with nonlocal and nonlinear response. Proceedings of SPIE, 2003, vol. 5216,pp. 127–138.https://doi.org/10.1117/12.509138
  29. BruderF.-K., DeuberF., FäckeT., HagenR., HönelD., JurbergsD., RölleT., WeiserM.-S. Reaction-diffusion model applied to high resolution Bayfol HX photopolymer. Proceedings of SPIE,2010, vol. 7619, pp. 76190I. https://doi.org/10.1117/12.841956


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