doi: 10.17586/2226-1494-2022-22-5-999-1006


The beating effect in uniaxial oriented polymer materials

V. V. Golovina, P. P. Rymkevich, O. V. Rymkevich


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Golovina V.V., Rymkevich P.P., Rymkevich O.V. The beating effect in uniaxial oriented polymer materials. Scientific and Technical Journal of Information Technologies, Mechanics and Optics, 2022, vol. 22, no. 5, pp. 999–1006 (in Russian). doi: 10.17586/2226-1494-2022-22-5-999-1006


Abstract
Elastic-relaxation properties of uniaxial oriented polymer materials under dynamic deformation mode are investigated. A theoretical explanation of the phenomenon of the occurrence of beats is proposed. Experimental confirmation of the obtained theoretical results is given. Using the barrier theory and applying the balance equation of the number of cluster transitions through the energy barrier, taking into account the transition time, a refined constitutive equation of the viscoelasticity of the polymer materials is obtained. Experimental studies in the dynamic mode were carried out by the method of the longitudinal low-amplitude oscillations. For a polymer material, taking into account the time of transition of the cluster through the energy barrier, a refined constitutive equation is obtained. The resulting equation is a second-order differential equation and admits a periodic solution. The application of the obtained equation to the study of free longitudinal low-amplitude oscillations in uniaxial oriented polymer materials is considered. It is shown that the solution of the equation admits two close complex roots, the existence of which leads to the effect of the observed beats. The relations between the parameters of the oscillatory process and viscoelastic characteristics are obtained. The experiment showed that the polymer materials under study have a complex form of the oscillatory process, similar to the phenomenon of beats, in a certain range of load. The dependence of the tangent of the mechanical losses angle calculated from the main frequency on the stress has an acute maximum in the stress range where beats are observed. According to the obtained theoretical ratios and experimentally determined attenuation coefficient and main frequency, the time of transition of the cluster through the energy barrier or the lifetime of the cluster in this energy state is determined. The use of additional information obtained during experiments in static modes made it possible to determine the relaxation time for this material. The calculation on the example of polyethyleneterephthalate (PET) filament showed that the theory is consistent with the experiment. Based on the experimental data obtained during the study of free longitudinal oscillations and the solution of the refined constitutive equation, it is possible to determine the necessary viscoelastic characteristics which makes it possible to predict dynamic deformation processes in polymer materials.

Keywords: constitutive equation, viscoelasticity, highly elastic deformation, free longitudinal oscillations, beating, uniaxial oriented polymers

References
  1. Mandelshtam L.I. Lectures on the Theory of Oscillations. Moscow, Nauka Publ., 1972, 470 p. (in Russian)
  2. Rabotnov Iu.N. Elements of Hereditary Solid Mechanics . Moscow, Nauka Publ., 1977, 284 p. (in Russian)
  3. Palmov V.A. Nonlinear Mechanics of Deformable Bodies. St. Petersburg, Polytechnic University Publ., 2014. 793 с. (in Russian)
  4. Romanova A.A., Stalevich A.M., Rymkevich P.P., Gorshkov A.S., Ginzburg B.M. A new phenomenon – amplitude-modulated free oscillations (beatings) in loaded, highly oriented fibers from semicrystalline polymers. Journal of Macromolecular Science. Part B: Physics, 2007, vol. 46B, no. 3, pp. 467–474. https://doi.org/10.1080/00222340701257703
  5. Romanova A.A. Mathematical modeling of the synthetic threads deformation properties under dynamic loading. Dissertation for the degree of candidate of technical sciences, Leningrad, 1990, 231 p. (in Russian)
  6. Gorshkov A.S. Dynamic viscoelasticity of the synthetic threads at the initial deformation stage. Dissertation for the degree of candidate of technical sciences. St. Petersburg, 2004, 178 p. (in Russian)
  7. Romanova A.A., Rymkevich P.P., Gorshkov A.S., Stalevich A.M. Dynamic relaxation of synthetic fibres. Fibre Chemistry, 2005, vol. 37, no. 4, pp. 289–292. https://doi.org/10.1007/s10692-005-0097-2
  8. Gunn J.B. Microwave oscillations of current in III-V semiconductors. Solid State Communications, 1963, vol. 1, no. 4, pp. 88–91. https://doi.org/10.1016/0038-1098(63)90041-3
  9. Belousov B.P. Intermittent reaction and its mechanism. Autowave processes in systems with diffusion. Gorky, State University of Gorky, 1951, pp. 76. (inRussian)
  10. Zhabotinskii A.M. Concentration Oscillations. Moscow, Nauka Publ., 1974, 179 p. (in Russian)
  11. Gorshkov A.S., Romanova A.A., Rymkevich P.P., Stalevich A.M. Amplitude Modulation of Oriented Polymers at the Initial Stage of Deformation. Fiziko-himija polimerov: Sintez, svojstva i primenenie, 2004, no. 10, pp. 111–112. (in Russian)
  12. Rymkevich P.P., Romanova A.A., Golovina V.V., Makarov A.G. The energy barriers model for the physical description of the viscoelasticity of synthetic polymers: application to the uniaxial orientational drawing of polyamide films. Journal of Macromolecular Science. Part B: Physics, 2013, vol. 52, no. 12, pp. 1829–1847. https://doi.org/10.1080/00222348.2013.808906
  13. Golovina V.V. Modeling and Prediction of Deformation Properties of Polymer Textile Materials. Dissertation for the degree of candidate of technical sciences. St. Petersburg, 2013, 168 p. (in Russian)
  14. Rymkevich P.P. Development of Scientific Foundations and Prediction Methods for the Thermoviscoelastic Properties of Polymeric Materials in the Textile and Consumer Industry. Dissertation for the degree of doctor of technical sciences. St. Petersburg, SPbSUITD, 2018, 299 p. (in Russian)
  15. Golovina V.V., Lyashenko V.A., Basenko V.G., Rymkevich O.V. Predicting the mechanical behavior of polymer textile materials taking into account their supermolecular structure. Proceedings of the higher educational institutions. Light Industry Technology, 2017, vol. 36, no. 2, pp. 36–40. (in Russian)
  16. Golovina V.V., Makarov A.G., Romanova A.A., Rymkevich O.V. Modeling and forecasting of the polymer textile creep by the barrier theory method. Proceedings of the higher educational institutions. Light Industry Technology, 2018, vol. 41, no. 3, pp. 5–9. (in Russian)
  17. Gorshkov A.S., Makarov A.G., Romanova A.A., Rymkevich P.P. Modelling of directed polymers deformation processes based on the description of the kinetics of supramolecular structures separated by energy barriers. Magazine of Civil Engineering, 2013, no. 9(44), pp. 75–83. (in Russian). https://doi.org/10.5862/MCE.44.10
  18. Golovina V.V., Shakhova E.A., Rymkevich P.P. Condition equation of polymer filaments. Scientific and Technical Journal of Information Technologies, Mechanics and Optics, 2020, vol. 20, no. 6, pp. 877–882. (inRussian). https://doi.org/10.17586/2226-1494-2020-20-6-877-882
  19. Gorshkov A.S., Stalevich A.M., Romanova A.A., Rymkevich P.P. Device for determining the dynamic characteristics of complex threads. Patent RU33650U1. 2003. (in Russian)


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