doi: 10.17586/2226-1494-2024-24-5-866-870


Spectral dependence of photoelecrochemical water splitting by silver nanoporous layers

A. I. Sidorov, A. V. Nashchekin, N. V. Nikonorov


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Sidorov A.I., Nashchekin A.V., Nikonorov N.V. Spectral dependence of photoelecrochemical water splitting by silver nanoporous layers. Scientific and Technical Journal of Information Technologies, Mechanics and Optics, 2024, vol. 24, no. 5, pp. 866–870 (in Russian). doi: 10.17586/2226-1494-2024-24-5-866-870


Abstract
The article presents the results of the spectral dependence study of the quantum efficiency of photocatalytic water decomposition. The relationship between the radiation spectrum and the efficiency of photocatalytic water decomposition into hydrogen and oxygen is determined. For this purpose, an electrolyte based on sodium nitrate is studied. The photocathode contained nanoporous silver layers. It is shown that the maximum quantum efficiency of photocatalytic water decomposition by spectrum integrally amounts to 1.9 %, and increases with decreasing radiation wavelength. The obtained results can be used in the development of solar energy devices designed for photocatalytic water decomposition into hydrogen and oxygen. 

Keywords: photocatalysis, nanoporous layer, silver, water splitting

Acknowledgements. This work was financially supported by the Russian Science Foundation (Project No. 20-19-00559). SEM characterization were performed using equipment owned by the Federal Joint Research Center “Material Science and Characterization in Advanced Technology” with financial support by the Ministry of Education and Science of the Russian Federation.

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